Stephan Gerald, Näther Christian, Tuczek Felix
Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Olshausenstrasse 40, D-24098 Kiel, Germany.
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 10;64(Pt 5):m629. doi: 10.1107/S1600536808008635.
In the crystal structure of the title compound, MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis-(diphenyl-phosphino)ethane and one 2-[bis-(diphenyl-phosphinometh-yl)amino]pyridinium ligand. The remaining binding sites of the distorted octa-hedron are occupied by a hydrazidate (NNH(2) (2-)) and a fluoride ligand. Two F atoms of an anion are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.
在标题化合物MoF(N₂H₂)(C₃₁H₂₉N₂P₂)(C₂₆H₂₄P₂)₂的晶体结构中，每个钼原子被一个1,2-双（二苯基膦基）乙烷和一个2-[双（二苯基膦基甲基）氨基]吡啶鎓配体的四个磷原子所包围。畸变八面体的其余配位位点被一个酰肼基（NNH₂²⁻）和一个氟配体占据。阴离子的两个氟原子在两个位置上无序；位点占有率约为0.7和0.3。
