Fu Baoci, Zhao Chang-Qiu
College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 17;66(Pt 4):o859. doi: 10.1107/S1600536810009219.
The title compound, C(22)H(35)O(3)P, features a tetra-hedral P atom bonded to a phenyl ring, a hydroxy-cyclo-hexyl unit and the O atom of a menthyl group. The axial chirality at phospho-rus is R(P). In the crystal, mol-ecules are connected through O-H⋯O hydrogen bonds involving the hydr-oxy and P=O groups, forming chains along the 2(1) screw axis. The methyl groups of the isopropyl fragment in the menthyl unit are disordered over two sites of equal occupancy.
标题化合物C(22)H(35)O(3)P的特征是一个四面体磷原子与一个苯环、一个羟基环己基单元以及一个薄荷基的氧原子相连。磷原子处的轴手性为R(P)。在晶体中，分子通过涉及羟基和P=O基团的O-H⋯O氢键相连，沿2(1)螺旋轴形成链状结构。薄荷基单元中异丙基片段的甲基在两个占有率相等的位置上无序分布。
