6-乙酰氧基甲基-3-[(2-羟基-3-甲氧基亚苄基)氨基]-3,4,5,6-四氢-2H-吡喃-2,4,5-三基三乙酸酯
6-Acetoxy-methyl-3-[(2-hydr-oxy-3-methoxy-benzyl-idene)amino]-3,4,5,6-tetra-hydro-2H-pyran-2,4,5-triyl triacetate.
作者信息
Wang Yan Fei, Zhang Shu-Hua, Chen Zhen Feng, Liang Hong
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 31;66(Pt 4):o990. doi: 10.1107/S1600536810011475.
Abstract
The title compound, C(22)H(27)NO(11), was synthesized by the reaction of 4,5-diacet-oxy-6-acetoxy-methyl-3-amino-tetra-hydro-pyran-2-yl acetate and 2-hydr-oxy-3-methoxy-benzalde-hyde in ethanol. The mol-ecule contains two six-membered rings, one of which is in a chair conformation, and an intra-molecular O-H⋯N hydrogen bond is present.
摘要
标题化合物C(22)H(27)NO(11)是由4,5-二乙酰氧基-6-乙酰氧基甲基-3-氨基四氢吡喃-2-基乙酸酯与2-羟基-3-甲氧基苯甲醛在乙醇中反应合成的。该分子含有两个六元环，其中一个呈椅式构象，并且存在分子内O-H⋯N氢键。
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