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链状聚[四钠[[顺式二氧代-反式-双(硫酸根-κO)钼酸(VI)]]-μ-硫酸根-κO:O']]

catena-Poly[tetra-sodium [[cis-dioxido-trans-bis-(sulfato-κO)molybdate(VI)]-μ-sulfato-κO:O']].

作者信息

Schäffer Susan J Cline, Berg Rolf W

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 15;64(Pt 11):i73. doi: 10.1107/S1600536808030328.

DOI:10.1107/S1600536808030328
PMID:21580809
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959510/
Abstract

Single crystals of the title compound, {Na(4)[Mo(VI)O(2)(SO(4))(3)]}(n), were grown from a melt of MoO(3) and Na(2)SO(4) in Na(2)S(2)O(7). In contrast to the structure of the isoformular K compound, K(4)[Mo(VI)O(2)(SO(4))(3)], with its monomeric anion, this sodium analogue contains a polymeric anion of the type {Mo(VI)O(2)(SO(4))(2)-μ-(SO(4))}(n). The Mo(VI) cations, surrounded by two tightly bonded O atoms and four O atoms of one bridging and two terminal sulfato ligands, form zigzag chains parallel to [100]. All four Na(+) cations are situated between the anionic chains and have distorted octa-hedral coordination spheres.

摘要

标题化合物{Na₄[Mo(VI)O₂(SO₄)₃]}ₙ的单晶是在Na₂S₂O₇中由MoO₃和Na₂SO₄的熔体生长而成。与其等化学式的K化合物K₄[Mo(VI)O₂(SO₄)₃]的结构不同，后者具有单体阴离子，而这种钠类似物包含一种{Mo(VI)O₂(SO₄)₂-μ-(SO₄)}ₙ型的聚合阴离子。Mo(VI)阳离子被两个紧密键合的O原子以及一个桥连硫酸根配体和两个端基硫酸根配体的四个O原子所包围，形成平行于[100]的锯齿链。所有四个Na⁺阳离子位于阴离子链之间，且具有扭曲的八面体配位球。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32ba/2959510/d31c64e89b9f/e-64-00i73-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32ba/2959510/85ea70001aa2/e-64-00i73-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32ba/2959510/d31c64e89b9f/e-64-00i73-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32ba/2959510/85ea70001aa2/e-64-00i73-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32ba/2959510/d31c64e89b9f/e-64-00i73-fig2.jpg

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本文引用的文献

1
Tetra-potassium cis-dioxido-trans-bis-(sulfato-κO)sulfato(κO,O')molybdate(VI).顺式二氧代-反式-双（硫酸根-κO）硫酸根（κO，O'）钼酸（VI）四钾盐
Acta Crystallogr Sect E Struct Rep Online. 2008 Feb 13;64(Pt 3):i20. doi: 10.1107/S1600536808003851.
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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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The reaction between ZnO and molten Na2S2O7 or K2S2O7 forming Na2Zn(SO4)2 orK2Zn(SO4)2, studied by Raman spectroscopy and x-ray diffraction.
通过拉曼光谱和X射线衍射研究了氧化锌（ZnO）与熔融的焦硫酸钠（Na2S2O7）或焦硫酸钾（K2S2O7）之间形成硫酸锌钠（Na2Zn(SO4)2）或硫酸锌钾（K2Zn(SO4)2）的反应。
Inorg Chem. 2005 May 16;44(10):3485-93. doi: 10.1021/ic0500513.
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Crystal structure and spectroscopic characterization of K8(VO)2O(SO4)6.
Inorg Chem. 2003 Nov 3;42(22):7123-8. doi: 10.1021/ic0301674.