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链状聚[[双[[双-(3-氨基丙基)胺-κN,N',N''](硫氰酸根合-κN)镉]-μ(4)-硫酸根合-κO,O:O',O']甲醇半溶剂化物]

catena-Poly[[bis-[[bis-(3-amino-prop-yl)amine-κN,N',N''](thio-cyanato-κN)cadmium]-μ(4)-sulfato-κO,O:O',O'] methanol hemisolvate].

作者信息

Boeckmann Jan, Näther Christian

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24098 Kiel, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1201-2. doi: 10.1107/S1600536811031163. Epub 2011 Aug 6.

DOI:10.1107/S1600536811031163
PMID:22058845
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3200697/
Abstract

The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thio-cyanate and one sulfate anion, two bis-(3-amino-prop-yl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one terminal N-bonded thio-cyanate anion and one bis-(3-amino-prop-yl)amine co-ligand, and by two O atoms of two symmetry-related sulfate anions, defining a slightly distorted octa-hedral coordination polyhedron. Each two Cd(2+) cations are connected into dimers, which are located on centres of inversion and which are further μ-1,1:3,3-bridged via the sulfate anions into polymeric zigzag chains along the a axis.

摘要

标题化合物{[Cd₂(NCS)₂(SO₄)(C₆H₁₇N₃)₂]·0.5CH₃OH}ₙ的不对称单元由两个Cd²⁺阳离子、两个硫氰酸根离子和一个硫酸根阴离子、两个双（3-氨基丙基）胺共配体以及一个占据率为一半的甲醇分子组成。每个Cd²⁺阳离子由一个末端N键合硫氰酸根阴离子的四个N原子和一个双（3-氨基丙基）胺共配体配位，以及两个对称相关硫酸根阴离子的两个O原子配位，形成一个略微扭曲的八面体配位多面体。每两个Cd²⁺阳离子连接成二聚体，这些二聚体位于对称中心，并通过硫酸根阴离子进一步以μ-1,1:3,3-桥连方式沿a轴形成聚合物之字形链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12f9/3200697/7d64baa8da02/e-67-m1201-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12f9/3200697/cda7b2d3dc7b/e-67-m1201-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12f9/3200697/7d64baa8da02/e-67-m1201-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12f9/3200697/cda7b2d3dc7b/e-67-m1201-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12f9/3200697/7d64baa8da02/e-67-m1201-fig2.jpg

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本文引用的文献

1
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2
A rational route to SCM materials based on a 1-D cobalt selenocyanato coordination polymer.基于一维钴硒氰酸配位聚合物的 SCM 材料的合理路线。
Chem Commun (Camb). 2011 Jul 7;47(25):7104-6. doi: 10.1039/c1cc12273h. Epub 2011 May 27.
3
Solid-state transformation of [Co(NCS)2(pyridine)4] into [Co(NCS)2(pyridine)2]n: from Curie-Weiss paramagnetism to single chain magnetic behaviour.[Co(NCS)2(pyridine)4]到[Co(NCS)2(pyridine)2]n的固态相变：从居里-外斯顺磁体到单链磁体行为。
Dalton Trans. 2010 Dec 7;39(45):11019-26. doi: 10.1039/c0dt00904k. Epub 2010 Oct 14.
4
Rational design of bridging selenocyanates by thermal decomposition reactions.通过热分解反应合理设计桥连硒氰酸盐。
Chem Commun (Camb). 2010 Jul 14;46(26):4707-9. doi: 10.1039/c0cc00064g.
5
Thermal decomposition reactions as tool for the synthesis of new metal thiocyanate diazine coordination polymers with cooperative magnetic phenomena.热分解反应作为一种新的金属硫氰酸根二嗪配位聚合物的合成工具，具有协同磁现象。
Inorg Chem. 2009 Jul 20;48(14):6896-903. doi: 10.1021/ic9002498.
6
Coordination polymer changing its magnetic properties and colour by thermal decomposition: synthesis, structure and properties of new thiocyanato iron(II) coordination polymers based on 4,4'-bipyridine as ligand.通过热分解改变磁性和颜色的配位聚合物：基于4,4'-联吡啶作为配体的新型硫氰酸根合铁（II）配位聚合物的合成、结构与性质
Dalton Trans. 2009 Oct 14(38):7975-84. doi: 10.1039/b907645j. Epub 2009 Aug 12.
7
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.