N,N-二甲基-N-丙基-1-氯化铵一水合物
N,N-Dimethyl-N-propyl-propan-1-aminium chloride monohydrate.
作者信息
Kärnä Minna, Lahtinen Manu, Valkonen Jussi
机构信息
University of Jyväskylä, Department of Chemistry, PO Box 35, FIN-40014 JY, Finland.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 11;64(Pt 11):o2100. doi: 10.1107/S1600536808032340.
The title compound, C(8)H(20)N(+)·Cl(-)·H(2)O, has been prepared by a simple one-pot synthesis route followed by anion exchange using resin. In the crystal structure, the cations are packed in such a way that channels exist parallel to the b axis. These channels are filled by the anions and water mol-ecules, which inter-act via O-H⋯Cl hydrogen bonds [O⋯Cl = 3.285 (3) and 3.239 (3) Å] to form helical chains. The cations are involved in weak inter-molecular C-H⋯Cl and C-H⋯O hydrogen bonds. The title compound is not isomorphous with the bromo or iodo analogues.
标题化合物C₈H₂₀N⁺·Cl⁻·H₂O是通过一种简单的一锅合成路线制备的，随后使用树脂进行阴离子交换。在晶体结构中，阳离子以这样的方式堆积，即存在平行于b轴的通道。这些通道被阴离子和水分子填充，它们通过O—H⋯Cl氢键[O⋯Cl = 3.285 (3) 和3.239 (3) Å]相互作用形成螺旋链。阳离子参与弱的分子间C—H⋯Cl和C—H⋯O氢键。标题化合物与溴代或碘代类似物不同晶型。
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