（E）-4- [（1,5-二甲基-3-氧代-2-苯基-2,3-二氢-1H-吡唑-4-基）亚氨基甲基]苯基 4-溴苯磺酸盐
(E)-4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino-meth-yl]phenyl 4-bromo-benzene-sulfonate.
作者信息
Han Jian-Rong, Tian Xia, Zhen Xiao-Li, Li Zhen-Chao, Liu Shou-Xin
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 31;64(Pt 11):o2244. doi: 10.1107/S1600536808035034.
Abstract
In the title compound, C(24)H(20)BrN(3)O(4)S, the central benzene ring makes dihedral angles of 17.13 (13), 39.83 (13) and 58.37 (13)°, respectively, with the pyrazolone ring, the bromo-benzene ring and the terminal phenyl ring. In the crystal structure, the packing is stabilized by a weak non-classical inter-molecular C-H⋯O hydrogen bond which links the mol-ecules into a chain propagating in [100].
摘要
在标题化合物C₂₄H₂₀BrN₃O₄S中，中心苯环与吡唑啉酮环、溴苯环和末端苯环分别形成的二面角为17.13 (13)°、39.83 (13)°和58.37 (13)°。在晶体结构中，堆积通过一个弱的非经典分子间C—H⋯O氢键得以稳定，该氢键将分子连接成在[100]方向传播的链。
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本文引用的文献
1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
2-Acetylpyridine thiosemicarbazones. 1. A new class of potential antimalarial agents.2-乙酰吡啶硫代半卡巴腙。1. 一类新型潜在抗疟药。
J Med Chem. 1979 Jul;22(7):855-62. doi: 10.1021/jm00193a020.
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