三（1,10-菲咯啉-κN,N'）铁（II）μ-氧代-双[三氯合铁（III）]乙醇半溶剂化物
Tris(1,10-phenanthroline-κN,N')iron(II) μ-oxido-bis[trichloridoferrate(III)] ethanol hemisolvate.
作者信息
Li Zhan-Xian, Yu Ming-Ming, Zhang Yu-Na, Wei Liu-He
机构信息
Department of Chemistry, Zhengzhou University, Zhengzhou 450001, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):m1514. doi: 10.1107/S1600536808035897.
The title compound, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O]·0.5CH(3)CH(2)OH, consists of one Fe(phen)(3) cation (phen = 1,10-phen-anthroline), one Fe(2)Cl(6)O anion and one half-mol-ecule of ethanol. In the cation, the Fe(II) atom is coordinated by six N atoms from three phen ligands in a distorted octa-hedral geometry. In the bent anion, two Fe(III) atoms are connected by a bridging oxide O atom [bridging angle = 160.6 (4)°], and each Fe(III) atom is also coordinated by three Cl atoms, completing a distorted tetra-hedral geometry.
标题化合物[Fe(C₁₂H₈N₂)₃][Fe₂Cl₆O]·0.5CH₃CH₂OH由一个[Fe(phen)₃]²⁺阳离子（phen = 1,10 - 菲咯啉）、一个[Fe₂Cl₆O]²⁻阴离子和半个乙醇分子组成。在阳离子中，Fe(II)原子由来自三个phen配体的六个N原子以扭曲的八面体几何构型配位。在弯曲的阴离子中，两个Fe(III)原子通过一个桥连的氧化物O原子相连[桥连角 = 160.6 (4)°]，并且每个Fe(III)原子还由三个Cl原子配位，形成一个扭曲的四面体几何构型。
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