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三（1,10-菲咯啉）铁（II）μ-氧代-双-[三氯合铁（III）]

Tris(1,10-phenanthroline)iron(II) μ-oxido-bis-[trichloridoferrate(III)].

作者信息

Ling Chun, Song Li, Wang Xinping

机构信息

Department of Chemistry, Key Laboratory of Advanced Textile Materials and Manufacturing Technology of the Education Ministry, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1232-3. doi: 10.1107/S1600536811031783. Epub 2011 Aug 11.

DOI:10.1107/S1600536811031783
PMID:22065697
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3200904/
Abstract

In the title salt, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O], the ionic components are linked into a two-dimensional supra-molecular layer by two pairs of C-H⋯Cl hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent Fe(II)-Fe(III) compound, in which an Fe(II) atom is coordinated by three phen ligands, forming a six-coordinated cationic entity and the anionic part is formed by two Fe(III) atoms in tetra-hedral coordination environments constructed by three chloride ions and one bridging oxide ligand. Intra-molecular C-H⋯N hydrogen bonds are observed.

摘要

在标题盐[Fe(C₁₂H₈N₂)₃][Fe₂Cl₆O]中，离子组分通过两对C-H⋯Cl氢键和π-π堆积相互作用[质心-质心距离 = 3.655 (4) 和3.498 (3) Å]连接成二维超分子层。该盐被表征为一种混合价态的Fe(II)-Fe(III)化合物，其中一个Fe(II)原子由三个菲咯啉配体配位，形成一个六配位的阳离子实体，阴离子部分由两个处于四面体配位环境的Fe(III)原子组成，该环境由三个氯离子和一个桥连氧化物配体构成。观察到分子内的C-H⋯N氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ad1/3200904/fd8a7c2cb558/e-67-m1232-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ad1/3200904/30e222edd7a6/e-67-m1232-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ad1/3200904/77003232f43b/e-67-m1232-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ad1/3200904/fd8a7c2cb558/e-67-m1232-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ad1/3200904/30e222edd7a6/e-67-m1232-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ad1/3200904/77003232f43b/e-67-m1232-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ad1/3200904/fd8a7c2cb558/e-67-m1232-fig3.jpg

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本文引用的文献

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