[3 -（二甲基氨基）苯甲酸根合]三苯基锡（IV）
[3-(Dimethyl-amino)benzoato]triphenyl-tin(IV).
作者信息
Win Yip Foo, Teoh Siang Guan, Ha Sie Tiong, Kia Reza, Fun Hoong-Kun
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 13;64(Pt 12):m1530-1. doi: 10.1107/S1600536808036337.
In the title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NO(2))], the Sn atom is coordinated by three phenyl groups and a carboxyl-ate anion in a distorted tetra-hedral geometry. An intra-molecular C-H⋯O inter-action forms an S(7) ring motif. The dihedral angles between the benzoate group and the other three phenyl rings are 76.94 (8), 66.82 (8) and 42.34 (9)°. The crystal structure is further stabilized by inter-molecular C-H⋯π inter-actions.
在标题化合物[Sn(C₆H₅)₃(C₉H₁₀NO₂)]中，Sn原子由三个苯基和一个羧酸根阴离子以扭曲的四面体几何构型配位。分子内的C—H⋯O相互作用形成了一个S(7)环 motif。苯甲酸酯基团与其他三个苯环之间的二面角分别为76.94 (8)°、66.82 (8)°和42.34 (9)°。晶体结构通过分子间的C—H⋯π相互作用进一步稳定。
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