链状聚[[[二碘化汞（II）]-μ-N，N'-二-3-吡啶基吡啶-2,6-二甲酰胺]二甲基甲酰胺溶剂合物]
catena-Poly[[[diiodidomercury(II)]-μ-N,N'-di-3-pyridylpyridine-2,6-dicarboxamide] dimethyl-formamide solvate].
作者信息
Huang Li-Hua, Wu Jie, Pan Fang-Fang
机构信息
Department of Chemistry, Zhengzhou University, Zhengzhou 450052, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 13;64(Pt 12):m1533. doi: 10.1107/S1600536808036581.
Abstract
In the title complex, {[HgI(2)(C(17)H(13)N(5)O(2))]·C(3)H(7)NO}(n), the Hg atom is coordinated by two I atoms and two N atoms from two different ligands in a distorted tetra-hedral environment. Hg atoms are bridged by N,N'-di-3-pyridylpyridine-2,6-dicarboxamide ligands, forming a helical chain running along the a axis.
摘要
在标题配合物{[HgI₂(C₁₇H₁₃N₅O₂)]·C₃H₇NO}ₙ中，汞原子在扭曲的四面体环境中由来自两个不同配体的两个碘原子和两个氮原子配位。汞原子由N,N'-二(3-吡啶基)吡啶-2,6-二甲酰胺配体桥连，形成沿a轴延伸的螺旋链。
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