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链状聚[[水合-(2,2'-联吡啶)钴(II)]-μ-5-硝基-间苯二甲酸根]

catena-Poly[[aqua-(2,2'-bipyridyl)cobalt(II)]-μ-5-nitro-isophthalato].

作者信息

Liu Ying, He Qingpeng, Zhang Xianxi, Xue Zechun, Lv Chunyan

机构信息

College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):m1605-6. doi: 10.1107/S1600536808038178.

Abstract

In the crystal structure of the title compound, Co(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O), there are two symmetry-independent one-dimensional coordination polymers, which are approximately related by noncrystallographic inversion symmetry. Each zigzag chain is constructed from one Co(II) ion, one O-monodentate 5-nitro-isophthalate (ndc) dianion, one N,N'-bidentate 2,2'-bipyridyl ligand and one water mol-ecule. A symmetry-generated O,O'-bidentate ndc dianion completes the cobalt coordination environment, which could be described as very distorted cis-CoN(2)O(4) octa-hedral. The bridging ndc ligands result in parallel chains running along the a direction, and O-H⋯O hydrogen bonds arising from the water mol-ecules complete the structure.

摘要

在标题化合物[Co(C₈H₃NO₆)(C₁₀H₈N₂)(H₂O)]ₙ的晶体结构中,存在两个对称独立的一维配位聚合物,它们通过非晶体学反演对称性大致相关。每条锯齿链由一个Co(II)离子、一个O-单齿5-硝基间苯二甲酸(ndc)二价阴离子、一个N,N'-双齿2,2'-联吡啶配体和一个水分子构成。一个通过对称性产生的O,O'-双齿ndc二价阴离子完善了钴的配位环境,其可被描述为严重扭曲的顺式-CoN₂O₄八面体。桥连的ndc配体导致平行链沿a方向延伸,由水分子形成的O-H⋯O氢键完善了该结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c968/2960127/3de06cf31741/e-64-m1605-fig1.jpg

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