水合氯{1-[1-(4-羟基苯基)-1H-四唑-5-基硫烷基]乙酸根}(甲醇)(1,10-菲咯啉)锰(II)
Aqua-chlorido{1-[1-(4-hydroxy-phen-yl)-1H-tetra-zol-5-ylsulfan-yl]acetato}(methanol)(1,10-phenanthroline)manganese(II).
作者信息
Yin Jian-Ling, Feng Yun-Long
机构信息
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):m1609. doi: 10.1107/S1600536808038245.
The title complex, [Mn(C(9)H(7)N(4)O(3)S)Cl(C(12)H(8)N(2))(CH(4)O)(H(2)O)], contains an Mn(II) ion six-coordinated by one O atom from the 2-[1-(4-hydroxy-phen-yl)-1H-tetra-zol-5-ylsulfan-yl]-acetate ligand, two N atoms from a chelating 1,10-phenanthroline ligand, one O atom from a methanol mol-ecule, one Cl atom and one water mol-ecule in a distorted octa-hedral coordination geometry. The existence of O-H⋯Cl, O-H⋯N and O-H⋯O hydrogen bonds further produces a two-dimensional structure.
标题配合物[Mn(C₉H₇N₄O₃S)Cl(C₁₂H₈N₂)(CH₄O)(H₂O)]包含一个Mn(II)离子，它由2-[1-(4-羟基苯基)-1H-四唑-5-基硫烷基]乙酸酯配体的一个O原子、螯合的1,10-菲咯啉配体的两个N原子、甲醇分子的一个O原子、一个Cl原子和一个水分子以扭曲的八面体配位几何构型六配位。O—H⋯Cl、O—H⋯N和O—H⋯O氢键的存在进一步产生了二维结构。
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