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二-μ-氯代-双-{水合氯代[3-乙基-4-苯基-5-(2-吡啶基)-4H-1,2,4-三唑-κN,N]锰(II)}

Di-μ-chlorido-bis-{aqua-chlorido[3-ethyl-4-phenyl-5-(2-pyrid-yl)-4H-1,2,4-triazole-κN,N]manganese(II)}.

作者信息

Wang Zuoxiang, Gong Ixaoning, Liu Chunyi, Zhang Xiaoming

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m157. doi: 10.1107/S1600536808044103.

DOI:10.1107/S1600536808044103
PMID:21581769
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968385/
Abstract

In the centrosymmetric dinuclear title compound, [Mn(2)Cl(4)(C(15)H(14)N(4))(2)(H(2)O)(2)], the Mn(II) atom is coordinated by an N,N'-bidentate ligand, a water mol-ecule, a terminal chloride ion and two bridging chloride ions in a distorted MnN(2)OCl(3) octa-hedral geometry. The Mn⋯Mn separation is 3.6563 (9) Å. In the crystal structure, O-H⋯N and O-H⋯Cl hydrogen bonds help to establish the packing.

摘要

在中心对称的双核标题化合物[Mn₂Cl₄(C₁₅H₁₄N₄)₂(H₂O)₂]中，Mn(II)原子由一个N,N'-双齿配体、一个水分子、一个端基氯离子和两个桥连氯离子配位，形成扭曲的MnN₂OCl₃八面体几何构型。Mn⋯Mn间距为3.6563 (9) Å。在晶体结构中，O—H⋯N和O—H⋯Cl氢键有助于确定堆积方式。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c567/2968385/07fb7e85657d/e-65-0m157-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c567/2968385/07fb7e85657d/e-65-0m157-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c567/2968385/07fb7e85657d/e-65-0m157-fig1.jpg

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