Suppr超能文献

2-[(E)-4-(二甲基氨基)亚苄基肼基]-5-硝基苯甲酸乙酯

Ethyl 2-[(E)-4-(dimethyl-amino)benzyl-idenehydrazino]-5-nitro-benzoate.

作者信息

Fun Hoong-Kun, Adhikari Adithya, Patil P S, Kalluraya B, Chantrapromma Suchada

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):o2286-7. doi: 10.1107/S1600536808035939.

Abstract

The title compound, C(18)H(20)N(4)O(4), exists in the E configuration with respect to the C=N bond of the methyl-idine unit. The dihedral angle between the two benzene rings is 9.01 (6)°. An intra-molecular N-H⋯O hydrogen bond involving the benzoate unit generates an S(6) ring motif. In the crystal, the mol-ecules are linked by weak C-H⋯O inter-actions into infinite chains along the b axis. These chains are further connected into sheets parallel to the ab plane which are stacked approximately along the c axis. A C-H⋯π inter-action is also observed.

摘要

标题化合物C(18)H(20)N(4)O(4)相对于亚甲基单元的C=N键以E构型存在。两个苯环之间的二面角为9.01 (6)°。涉及苯甲酸酯单元的分子内N-H⋯O氢键形成一个S(6)环模式。在晶体中,分子通过弱C-H⋯O相互作用沿b轴连接成无限长链。这些链进一步连接成平行于ab平面的片层,该片层大致沿c轴堆叠。还观察到C-H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0fe9/2959927/c1a430a532ba/e-64-o2286-fig1.jpg

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验