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2,3,4,9-四氢-1H-咔唑

2,3,4,9-Tetra-hydro-1H-carbazole.

作者信息

Murugavel S, Kannan P S, Subbiahpandi A, Surendiran T, Balasubramanian S

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 26;64(Pt 12):o2433. doi: 10.1107/S1600536808038713.

DOI:10.1107/S1600536808038713
PMID:21581401
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960078/
Abstract

In the title compound, C(12)H(13)N, two methyl-ene C atoms of the cyclo-hexene ring are disordered over two sites with occupancies of 0.591 (10) and 0.409 (10); both disorder components adopt half-chair conformations. The crystal structure is stabilized by inter-molecular N-H⋯π and C-H⋯π inter-actions.

摘要

在标题化合物C₁₂H₁₃N中，环己烯环的两个亚甲基C原子在两个位置上无序，占有率分别为0.591 (10)和0.409 (10)；两种无序组分均采用半椅式构象。晶体结构通过分子间的N-H⋯π和C-H⋯π相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2027/2960078/97faf3fafb15/e-64-o2433-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2027/2960078/97faf3fafb15/e-64-o2433-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2027/2960078/97faf3fafb15/e-64-o2433-fig1.jpg

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