一水合三氯·（1,10-菲咯啉-κN,N'）水合钴（II）氯化物
Triaqua-chlorido(1,10-phenanthroline-κN,N')cobalt(II) chloride monohydrate.
作者信息
Liu Yaru, Pan Yutian, Sun Junshan, Zhang Chuan
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 20;65(Pt 1):m114. doi: 10.1107/S1600536808042591.
In the title compound, [CoCl(C(12)H(8)N(2))(H(2)O)(3)]Cl·H(2)O, the Co(II) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand [Co-N = 2.125 (6) and 2.146 (6) Å], one chloride ligand [Co-Cl = 2.459 (2)Å] and three water mol-ecules [Co-O = 2.070 (5)-2.105 (5)Å] in a distorted octa-hedral geometry. Inter-molecular O-H⋯Cl and O-H⋯O hydrogen bonds form an extensive three-dimensional hydrogen-bonding network, which consolidates the crystal packing.
在标题化合物[CoCl(C₁₂H₈N₂)(H₂O)₃]Cl·H₂O中，Co(II)离子由1,10 - 菲咯啉配体的两个N原子[Co - N = 2.125 (6) 和2.146 (6) Å]、一个氯配体[Co - Cl = 2.459 (2) Å]以及三个水分子[Co - O = 2.070 (5) - 2.105 (5) Å]配位，形成扭曲的八面体几何构型。分子间的O - H⋯Cl和O - H⋯O氢键形成了广泛的三维氢键网络，巩固了晶体堆积。
Zotero 插件