三水合-(3-羧基-5-磺酸基苯甲酸根-κO)(1,10-菲咯啉-κN,N')钴(II)一水合物
Triaqua-(3-carb-oxy-5-sulfonatobenzoato-κO)(1,10-phenanthroline-κN,N')cobalt(II) monohydrate.
作者信息
Zhang Bing-Yu, Nie Jing-Jing, Xu Duan-Jun
机构信息
Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):m986. doi: 10.1107/S1600536808019843.
In the title compound, [Co(C(8)H(4)O(7)S)(C(12)H(8)N(2))(H(2)O)(3)]·H(2)O, the Co(II) cation is coordinated by one sulfoisophthalate dianion, one bidentate phenathroline (phen) mol-ecule and three water mol-ecules in a distorted cis-CoN(2)O(4) octa-hedral geometry. In the crystal structure, aromatic π-π stacking occurs [centroid-centroid distances 3.7630 (14) and 3.7269 (15) Å], as well as an extensive O-H⋯O and C-H⋯O hydrogen-bonding network.
在标题化合物[Co(C₈H₄O₇S)(C₁₂H₈N₂)(H₂O)₃]·H₂O中，Co(II)阳离子由一个磺基间苯二甲酸二阴离子、一个双齿邻菲罗啉（phen）分子和三个水分子配位，形成扭曲的顺式CoN₂O₄八面体几何构型。在晶体结构中，存在芳香π-π堆积[质心-质心距离为3.7630 (14)和3.7269 (15) Å]，以及广泛的O-H⋯O和C-H⋯O氢键网络。
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