氯代{ N,N'-邻亚苯基-[6,6'-亚乙基双(吡啶-2-甲酰胺)]}铁(III)
Chlorido{N,N'-o-phenyl-ene-[6,6'-ethyl-enebis(pyridine-2-carboxamide)]}iron(III).
作者信息
Yang Li, Tang Bin
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 10;65(Pt 1):m44. doi: 10.1107/S1600536808041354.
Abstract
In the title compound, [Fe(C(20)H(14)N(4)O(2))Cl], the Fe(III) ion is in a distorted square-pyramidal environment, with two pyridine and two deprotonated amide N atoms in the basal plane and the Cl ion in the apical position. The Fe(III) ion is displaced from the basal plane of the square- pyramid towards the apical Cl atom by 0.2942 (4) Å. The mol-ecules are linked into a three-dimensional network by C-H⋯Cl and C-H⋯O hydrogen bonds.
摘要
在标题化合物[Fe(C₂₀H₁₄N₄O₂)Cl]中，Fe(III)离子处于扭曲的四方锥环境中，两个吡啶和两个去质子化的酰胺N原子位于基面，Cl离子位于顶端位置。Fe(III)离子从四方锥的基面朝着顶端的Cl原子位移了0.2942(4) Å。分子通过C—H⋯Cl和C—H⋯O氢键连接成三维网络。
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