二氯{2-(吗啉-4-基)-N-[1-(吡啶-2-基)亚乙基]乙胺-κN,N',N''}铜(II)一水合物
Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl-idene]ethanamine-κN,N',N''}copper(II) monohydrate.
作者信息
Suleiman Gwaram Nura, Khaledi Hamid, Mohd Ali Hapipah
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 12;67(Pt 3):m334. doi: 10.1107/S1600536811004892.
In the title compound, [CuCl(2)(C(13)H(19)N(3)O)]·H(2)O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu(II) ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the apical position. In the crystal, O-H⋯Cl hydrogen bonds link the complex mol-ecules and the uncoordinated water mol-ecules into infinite chains along the a axis. The chains are further connected into a three-dimensional network via C-H⋯O and C-H⋯Cl inter-actions.
在标题化合物[CuCl₂(C₁₃H₁₉N₃O)]·H₂O中，三齿席夫碱配体和两个Cl原子在Cu(II)离子周围形成了一个扭曲的四方锥配位几何结构，其中三个N原子和一个Cl原子位于基面，另一个Cl原子位于顶点位置。在晶体中，O—H⋯Cl氢键将配合物分子和未配位的水分子沿a轴连接成无限链。这些链通过C—H⋯O和C—H⋯Cl相互作用进一步连接成三维网络。
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