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双（2,2'-联吡啶-κN,N'）（3,5-二硝基-2-氧化苯甲酸根-κO,O）钴（II）

Bis(2,2'-bipyridine-κN,N')(3,5-dinitro-2-oxidobenzoato-κO,O)cobalt(II).

作者信息

Zhong Chun-Long, Jiang Xiu-Rong, Wen De-Cai

机构信息

Department of Chemistry, Longyan University, Longyan, Fujian 364000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 17;65(Pt 1):m79. doi: 10.1107/S1600536808041974.

DOI:10.1107/S1600536808041974
PMID:21581544
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2967915/
Abstract

In the title compound, [Co(C(7)H(2)N(2)O(7))(C(10)H(8)N(2))(2)], the Co(II) atom is coordinated by four N atoms from two 2,2'-bipyridine ligands and two O atoms from a 3,5-dinitro-2-oxidobenzoate ligand, displaying a distorted octa-hedral coordination geometry. The crystal structure involves C-H⋯O hydrogen bonds between the 2,2'-bipyridine ligands and the carboxyl-ate and NO(2) groups of the 3,5-dinitro-2-oxidobenzoate ligand.

摘要

在标题化合物[Co(C₇H₂N₂O₇)(C₁₀H₈N₂)₂]中，Co(II)原子由来自两个2,2'-联吡啶配体的四个N原子和来自一个3,5-二硝基-2-氧化苯甲酸酯配体的两个O原子配位，呈现出扭曲的八面体配位几何构型。晶体结构涉及2,2'-联吡啶配体与3,5-二硝基-2-氧化苯甲酸酯配体的羧酸盐和NO₂基团之间的C-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c27a/2967915/2826af14fb16/e-65-00m79-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c27a/2967915/1bf8083bee2f/e-65-00m79-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c27a/2967915/2826af14fb16/e-65-00m79-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c27a/2967915/1bf8083bee2f/e-65-00m79-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c27a/2967915/2826af14fb16/e-65-00m79-fig2.jpg

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