Wu Jin-Cai
College of Chemistry and Chemical Engineering, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 17;65(Pt 1):m95. doi: 10.1107/S1600536808041858.
The title compound, [Al(CH(3))(2)(C(29)H(39)N(2)O(2))], exhibits disorder of one of the tert-butyl groups on the Schiff base ligand, where each methyl group is located over two sites, with occupancy factors of 0.57 (1) and 0.43 (1). The geometry around the Al(III) atom is distorted tetra-hedral, defined by two methyl groups, one N and one O atom from the Schiff base ligand.
标题化合物[Al(CH₃)₂(C₂₉H₃₉N₂O₂)]中,席夫碱配体上的一个叔丁基存在无序现象,其中每个甲基位于两个位置上,占有率分别为0.57 (1) 和0.43 (1)。Al(III)原子周围的几何构型为扭曲的四面体,由两个甲基、席夫碱配体中的一个N原子和一个O原子确定。