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二氯[2-({[3-(环己基氮鎓基)丙基]亚氨基}-甲基)-5-甲氧基-苯酚根]锌

Dichlorido[2-({[3-(cyclo-hexyl-aza-nium-yl)prop-yl]imino}-meth-yl)-5-meth-oxy-phenolate]zinc.

作者信息

Wang Chen-Yi

机构信息

Department of Chemistry, Huzhou University, Huzhou 313000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1085-6. doi: 10.1107/S1600536811027085. Epub 2011 Jul 13.

DOI:10.1107/S1600536811027085
PMID:22090862
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3212160/
Abstract

The title mononuclear zinc complex, [ZnCl(2)(C(17)H(26)N(2)O(2))], was obtained by the reaction of 2-hy-droxy-4-meth-oxy-benzaldehyde, N-cyclo-hexyl-propane-1,3-diamine and zinc chloride in methanol. The Zn(II) atom is four-coordinated by the phenolate O atom and imine N atom of the bidentate zwitterionic Schiff base ligand 2-{[3-(cyclo-hexyl-amino)-prop-yl]imino-meth-yl}-5-meth-oxy-phenol, and by two chloride ions, generating a distorted ZnONCl(2) tetra-hedral geometry. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming chains along the c-axis direction.

摘要

标题单核锌配合物[ZnCl₂(C₁₇H₂₆N₂O₂)]是通过2-羟基-4-甲氧基苯甲醛、N-环己基丙烷-1,3-二胺和氯化锌在甲醇中的反应得到的。Zn(II)原子由双齿两性离子席夫碱配体2-{[3-(环己基氨基)丙基]亚氨基甲基}-5-甲氧基苯酚的酚氧原子和亚胺氮原子以及两个氯离子四配位，形成扭曲的ZnONCl₂四面体几何构型。在晶体中，分子通过N-H⋯O氢键相连，沿c轴方向形成链状结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5134/3212160/ffbe3fe48c92/e-67-m1085-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5134/3212160/1e55f93e03dd/e-67-m1085-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5134/3212160/ffbe3fe48c92/e-67-m1085-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5134/3212160/1e55f93e03dd/e-67-m1085-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5134/3212160/ffbe3fe48c92/e-67-m1085-fig2.jpg

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