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3-间甲苯基-2-氧代-1-氧杂螺[4.4]壬-3-烯-4-基 2-(4-氯苯基)-3-甲基丁酸酯

3-Mesityl-2-oxo-1-oxaspiro-[4.4]non-3-en-4-yl 2-(4-chloro-phen-yl)-3-methyl-butyrate.

作者信息

Yu Chuan-Ming, Zhou Yong, Cheng Jing-Li, Zhao Jin-Hao

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 20;65(Pt 1):o183. doi: 10.1107/S1600536808043043.

Abstract

In the title compound, C(28)H(31)ClO(4), the five-membered cyclo-pentyl ring displays an envelope conformation with the atom at the flap position 0.519 (3) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 72.9 (1) and 82.4 (1)°, respectively, with the trimethyl- and chloro-phenyl rings. The dihedral angle between the two benzene rings is 15.3 (1)°. In the crystal, mol-ecules are linked through inter-molecular C-H⋯Cl hydrogen bonds, forming a chain running along the b axis.

摘要

在标题化合物C(28)H(31)ClO(4)中,五元环戊基环呈信封式构象,处于瓣位的原子偏离由其他四个原子形成的平均平面0.519 (3) Å。呋喃环与三甲基苯环和氯苯环的二面角分别为72.9 (1)°和82.4 (1)°。两个苯环之间的二面角为15.3 (1)°。在晶体中,分子通过分子间C—H⋯Cl氢键相连,形成沿b轴延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/10a4/2968092/a3c3d9a91a14/e-65-0o183-fig1.jpg

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