Ji Ming-Hua, Xia Min, Zhu Guo-Nian, Zhao Jin-Hao
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):o705. doi: 10.1107/S1600536809006503.
The title compound, C(24)H(23)ClO(4), is a potent insecticide and miticide. The five-membered cyclo-pentane ring displays an envelope conformation with the atom at the flap position 0.611 (2) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 71.3 (2) and 81.9 (2)°, respectively, with the 2,4,6-trimethyl-phenyl and 4-chloro-phenyl rings. The dihedral angle between the two benzene rings is 76.6 (1)°. In the crystal, mol-ecules are linked through weak inter-molecular C-H⋯O hydrogen bonds, forming chains running along the c axis.
标题化合物C(24)H(23)ClO(4)是一种高效杀虫剂和杀螨剂。五元环戊烷环呈信封式构象,处于瓣位的原子偏离由其他四个原子形成的平均平面0.611(2) Å。呋喃环与2,4,6-三甲基苯基环和4-氯苯基环分别形成71.3(2)°和81.9(2)°的二面角。两个苯环之间的二面角为76.6(1)°。在晶体中,分子通过弱分子间C—H⋯O氢键相连,形成沿c轴延伸的链。