Suppr超能文献

N-(3-溴-1,4-二氧代-1,4-二氢-2-萘基)-2-氯-N-(2-氯苯甲酰基)苯甲酰胺

N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth-yl)-2-chloro-N-(2-chloro-benzoyl)benzamide.

作者信息

Akinboye Emmanuel S, Butcher Ray J, Brandy Yakini, Adesiyun Tolulope A, Bakare Oladapo

机构信息

Department of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USA.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 6;65(Pt 1):o24. doi: 10.1107/S1600536808039214.

Abstract

The title compound, C(24)H(12)BrCl(2)NO(4), was synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 2-chloro-benzoyl chloride. The crystal structure shows that each of the chloro-phenyl rings is inclined at about 60° to the naphthoquinone ring system. The two chloro-phenyl rings adopt a conformation that ensures that chlorine substituents are anti so as to reduce electronic repulsion. An examination of the packing shows close O⋯Br and Cl⋯Cl contacts of 2.947 (2) and 3.346 (1) Å, respectively. In addition, the molecules are linked by weak intermolecular C-H⋯O and C-H⋯Cl interactions.

摘要

标题化合物C(24)H(12)BrCl(2)NO(4)由2-氨基-3-溴-1,4-萘醌和2-氯苯甲酰氯合成。晶体结构表明,每个氯苯环与萘醌环系统的夹角约为60°。两个氯苯环采取一种构象,以确保氯取代基呈反式排列,从而减少电子排斥。对堆积情况的研究表明,存在紧密的O⋯Br和Cl⋯Cl接触,距离分别为2.947 (2) Å和3.346 (1) Å。此外,分子通过弱的分子间C-H⋯O和C-H⋯Cl相互作用相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76cc/2967943/71e973c3244a/e-65-00o24-fig1.jpg

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验