4-氯-N-[N-(6-甲基-2-吡啶基)氨基甲硫酰基]苯甲酰胺
4-Chloro-N-[N-(6-methyl-2-pyrid-yl)car-bamo-thio-yl]benzamide.
作者信息
Binzet Gün, Emen Fatih Mehmet, Flörke Ulrich, Yeşilkaynak Tuncay, Külcü Nevzat, Arslan Hakan
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 10;65(Pt 1):o81-2. doi: 10.1107/S1600536808041123.
In the title compound, C(14)H(12)ClN(3)OS, the short exocyclic N-C bond lengths indicate resonance in the thiourea part of the mol-ecule. The title compound is stabilized by an intra-molecular N-H⋯N hydrogen bond, which results in the formation of a six-membered ring. In addition, it shows a synperiplanar conformation between the thio-carbonyl group and the pyridine group. Inter-molecular N-H⋯S and C-H⋯O inter-actions are also present.
在标题化合物C(14)H(12)ClN(3)OS中，短的环外N - C键长表明分子中硫脲部分存在共振。标题化合物通过分子内N - H⋯N氢键得以稳定，这导致形成了一个六元环。此外，它在硫羰基和吡啶基之间呈现出邻位交叉构象。分子间还存在N - H⋯S和C - H⋯O相互作用。
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