Chloridobis[diphenyl-glyoximato(1-)-κN,N'](1H-imidazole-κN)cobalt(III) hemihydrate.
作者信息
Meera P, Revathi C, Dayalan A
机构信息
Department of Chemistry, Loyola College (Autonomous), Chennai 600 034, Tamil Nadu, India.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m140-1. doi: 10.1107/S160053680804347X.
Abstract
The Co centre in the title compound, [Co(C(14)H(11)N(2)O(2))(2)Cl(C(3)H(4)N(2))]·0.5H(2)O, shows a slightly distorted octa-hedral coordination geometry. The glyoximate units of the mol-ecule are linked by O-H⋯O hydrogen bonds with the H atom almost in the middle of the two O atoms. The crystal packing is stabilized through inter-molecular N-H⋯O, N-H⋯N and O-H⋯Cl hydrogen bonds. The uncoordinated water mol-ecule shows half-occupation.
摘要
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