（N-正丁基-吡啶-4-碳硫酰胺-κN）二氯双（二甲基乙二肟-κN,N'）钴（III）半水合物
(N-n-Butyl-pyridine-4-carbothio-amide-κN)chloridobis(dimethyl-glyoximato-κN,N')cobalt(III) hemihydrate.
作者信息
Revathi C, Dayalan A, Sethusankar K
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m795-6. doi: 10.1107/S1600536809022661.
The title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol-ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa-hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O-H⋯O hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each mol-ecule are 2.07 (8) and 1.60 (1)°. The asymmetric unit contains a solvent water mol-ecule which is disordered over two sites with refined occupancies 0.64 (2) and 0.36 (2).
标题化合物反式-[Co(C₄H₇N₂O₂)₂Cl(C₁₀H₁₄N₂S)]·0.5H₂O的不对称单元中包含两个独立分子，其中Co(III)离子在略微扭曲的八面体配位环境中配位。占据赤道位置的双螯合乙二肟酸酯配体通过配体间的O—H⋯O氢键相连。每个分子中乙二肟酸酯配体平均平面之间的二面角分别为2.07 (8)°和1.60 (1)°。不对称单元包含一个溶剂水分子，该水分子在两个位置上无序分布，精修占有率分别为0.64 (2)和0.36 (2)。
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