（2,2'-联吡啶-κN,N'）（4-羟基-2-氧化苯甲醛硫代半卡巴腙合-κO,N,S）锌（II）
(2,2'-Bipyridine-κN,N')(4-hydr-oxy-2-oxidobenzaldehyde thio-semicar-ba-zon-ato-κO,N,S)zinc(II).
作者信息
Tan Kong Wai, Ng Chew Hee, Maah Mohd Jamil, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m143. doi: 10.1107/S1600536808043973.
Abstract
The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(10)H(8)N(2))], is N,N'-chelated by the heterocycle and N,O,S-chelated by the doubly deprotonated Schiff base ligand in a distorted square-pyramidal environment. O-H⋯O and N-H⋯N hydrogen bonds link adjacent mol-ecules into a layer structure.
摘要
在标题化合物[Zn(C₈H₇N₃O₂S)(C₁₀H₈N₂)]中，锌(II)原子在扭曲的四方锥环境中被杂环N,N'-螯合，并被双去质子化的席夫碱配体N,O,S-螯合。O—H⋯O和N—H⋯N氢键将相邻分子连接成层状结构。
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