[1-(4-羟基-2-氧化苄叉基)-4-苯基硫代氨基脲合-κN,O,S](1,10-菲啰啉-κN,N')锌(II)-4,4'-联吡啶(2/1)
[1-(4-Hydr-oxy-2-oxidobenzyl-idene)-4-phenyl-thio-semicarbazonato-κN,O,S](1,10-phenanthroline-κN,N')zinc(II)-4,4'-bipyridine (2/1).
作者信息
Tan Kong Wai, Ng Chew Hee, Maah Mohd Jamil, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 15;65(Pt 8):m920. doi: 10.1107/S1600536809026245.
Abstract
The Zn(II) atom in the title compound, [Zn(C(14)H(11)N(3)O(2)S)(C(12)H(8)N(2))]·0.5C(10)H(8)N(2), is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydr-oxy group of the Schiff base is a hydrogen-bond donor to 4,4'-bipyridine, which is located about a center of inversion, resulting in the formation of a supra-molecular trimeric unit.
摘要
在标题化合物[Zn(C₁₄H₁₁N₃O₂S)(C₁₂H₈N₂)]·0.5C₁₀H₈N₂中，Zn(II)原子在一个四方锥环境中被N-杂环N,N'-螯合，并被去质子化的席夫碱N,O,S-螯合。席夫碱的羟基是位于一个反演中心的4,4'-联吡啶的氢键供体，从而形成一个超分子三聚体单元。
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