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聚[双-(μ-半氢-2-苯基喹啉-4-羧酸根合-κN,O)银(I)]

Poly[bis-(μ-hemihydrogen 2-phenyl-quinoline-4-carboxyl-ato-κN,O)silver(I)].

作者信息

Zhang Xiutang, Wei Peihai, Li Bin

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 23;65(Pt 2):m223. doi: 10.1107/S1600536809001184.

DOI:10.1107/S1600536809001184
PMID:21581814
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968213/
Abstract

In the title compound, [Ag(C(16)H(10.5)NO(2))(2)], the Ag(I) cation (site symmetry 2) is coordinated by two N atoms in a near-linear AgN(2) arrangement. Two carboxyl-ate O atoms from two additional 2-phenyl-quinoline-4-carboxyl-ate ligands form long Ag-O bonds [2.6585 (17) Å], resulting in a distorted square-planar arrangement. The bridging ligands result in infinite corrugated sheets propagating in (010). An O-H⋯O hydrogen bond, disordered about a twofold axis, completes the structure.

摘要

在标题化合物[Ag(C₁₆H₁₀.₅NO₂)₂]中，Ag(I)阳离子（位点对称性为2）由两个N原子以近似线性的AgN₂排列方式配位。来自另外两个2-苯基喹啉-4-羧酸酯配体的两个羧酸根O原子形成长的Ag-O键[2.6585 (17) Å]，导致形成扭曲的平面正方形排列。桥连配体形成了在(010)方向延伸的无限波纹状片层。一个关于二重轴无序的O-H⋯O氢键完善了该结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e314/2968213/58a6d6dd0b16/e-65-0m223-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e314/2968213/fe03377f24ce/e-65-0m223-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e314/2968213/58a6d6dd0b16/e-65-0m223-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e314/2968213/fe03377f24ce/e-65-0m223-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e314/2968213/58a6d6dd0b16/e-65-0m223-fig2.jpg

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