3,3'-（2,2'-联-1H-咪唑-1,1'-二基）二丙醇
3,3'-(2,2'-Bi-1H-imidazole-1,1'-diyl)dipropanol.
作者信息
Zhang Tao, Liang Hong-Ze
机构信息
State Key Laboratory Base of Novel Functional Materials and Preparation Science, Institute of Solid Materials Chemistry, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):o213-4. doi: 10.1107/S1600536808043377.
In the title compound, C(12)H(18)N(4)O(2), unlike other unconjugated disubstituted biimidazole derivatives reported so far, the two imidazole rings in a trans conformation exhibit a large planar rotation angle of 51.27 (4)°, and consist of half-mol-ecule asymmetric units related by a twofold rotation. The mol-ecules are linked into a three-dimensional framework with a parallel laminated construction via O-H⋯N and C-H⋯O inter-actions.
在标题化合物C₁₂H₁₈N₄O₂中，与迄今报道的其他非共轭二取代联咪唑衍生物不同，呈反式构象的两个咪唑环展现出51.27 (4)°的大平面旋转角，且由通过二次旋转相关的半分子不对称单元组成。分子通过O—H⋯N和C—H⋯O相互作用连接成具有平行层状结构的三维骨架。
Zotero 插件