Kia Reza, Fun Hoong-Kun, Kargar Hadi
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 17;65(Pt 2):o338-9. doi: 10.1107/S1600536809001214.
In the title compound, C(9)H(9)ClN(2), a substituted imidazoline, the six- and five-membered rings are twisted from each other, making a dihedral angle of 17.07 (5)°. In the crystal structure, a short Cl⋯Cl [3.3540 (3) Å] inter-action is observed. Neighbouring mol-ecules are linked together by inter-molecular N-H⋯N hydrogen bonds into a one-dimensional infinite chain along the [101] direction and short Cl⋯Cl contacts link the chains into a three-dimensional network. There is also a significant π-stacking inter-action between the planar sections of the six- and five-membered rings.
在标题化合物C₉H₉ClN₂(一种取代咪唑啉)中,六元环和五元环相互扭曲,二面角为17.07(5)°。在晶体结构中,观察到短的Cl⋯Cl [3.3540(3)Å]相互作用。相邻分子通过分子间N-H⋯N氢键沿[101]方向连接成一维无限链,短的Cl⋯Cl接触将这些链连接成三维网络。六元环和五元环的平面部分之间还存在显著的π-堆积相互作用。