• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2-对甲苯基-4,5-二氢-1H-咪唑

2-p-Tolyl-4,5-dihydro-1H-imidazole.

作者信息

Kia Reza, Fun Hoong-Kun, Kargar Hadi

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 11;65(Pt 4):o724. doi: 10.1107/S1600536809008125.

DOI:10.1107/S1600536809008125
PMID:21582459
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968814/
Abstract

In the mol-ecule of the title compound, C(10)H(12)N(2), the six- and five-membered rings are almost co-planar, forming a dihedral angle of 3.56 (8)°. In the crystal structure, neighbouring mol-ecules are linked together by inter-molecular N-H⋯N hydrogen bonds into one-dimensional infinite chains along the c axis. The crystal structure, is further stabilized by weak inter-molecular C-H⋯π and π-π stacking [centroid-centroid distance = 3.8892 (9) Å] inter-actions.

摘要

在标题化合物C(10)H(12)N(2)的分子中，六元环和五元环几乎共面，形成的二面角为3.56 (8)°。在晶体结构中，相邻分子通过分子间N-H⋯N氢键沿c轴连接成一维无限链。晶体结构还通过弱的分子间C-H⋯π和π-π堆积[质心-质心距离 = 3.8892 (9) Å]相互作用进一步稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6a52/2968814/c2c1574f2f9a/e-65-0o724-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6a52/2968814/c944351261b3/e-65-0o724-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6a52/2968814/c2c1574f2f9a/e-65-0o724-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6a52/2968814/c944351261b3/e-65-0o724-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6a52/2968814/c2c1574f2f9a/e-65-0o724-fig2.jpg

相似文献

1
2-p-Tolyl-4,5-dihydro-1H-imidazole.2-对甲苯基-4,5-二氢-1H-咪唑
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 11;65(Pt 4):o724. doi: 10.1107/S1600536809008125.
2
2-[4-(4,5-Dihydro-1H-pyrrol-2-yl)phen-yl]-4,5-dihydro-1H-imidazole.2-[4-(4,5-二氢-1H-吡咯-2-基)苯基]-4,5-二氢-1H-咪唑
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):o2406. doi: 10.1107/S160053680803818X.
3
2-(4,5-Dihydro-1H-imidazol-2-yl)-pyridine.2-（4,5-二氢-1H-咪唑-2-基）吡啶
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 19;65(Pt 4):o780. doi: 10.1107/S1600536809009131.
4
2-(2-Thien-yl)-4,5-dihydro-1H-imidazole.2-（2-噻吩基）-4,5-二氢-1H-咪唑
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 14;65(Pt 2):o301. doi: 10.1107/S1600536809001068.
5
2-(3-Chloro-phen-yl)-4,5-dihydro-1H-imidazole.2-（3-氯苯基）-4,5-二氢-1H-咪唑
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 17;65(Pt 2):o338-9. doi: 10.1107/S1600536809001214.
6
2-(7,8-Diphenyl-1H-imidazo[4,5-f]quinoxalin-2-yl)phenol methanol disolvate.2 -（7,8 - 二苯基 - 1H - 咪唑并[4,5 - f]喹喔啉 - 2 - 基）苯酚甲醇溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 13;64(Pt 9):o1741-2. doi: 10.1107/S1600536808025269.
7
1-[2-(1H-Benzimidazol-2-yl)eth-yl]-1H-1,2,3-benzotriazole.1-[2-(1H-苯并咪唑-2-基)乙基]-1H-1,2,3-苯并三唑
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3167. doi: 10.1107/S1600536811045442. Epub 2011 Nov 5.
8
4-[(5-Hydr-oxy-3-methyl-1-phenyl-1H-pyrazol-4-yl)phenyl-meth-yl]-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol hemisolvate.4-[(5-羟基-3-甲基-1-苯基-1H-吡唑-4-基)苯甲基]-5-甲基-2-苯基-1H-吡唑-3(2H)-酮乙醇半溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 10;65(Pt 1):o66-7. doi: 10.1107/S1600536808039081.
9
2-(1H-Benzimidazol-1-yl)-1-(2-furyl)ethanone O-propyloxime.2-（1H-苯并咪唑-1-基）-1-（2-呋喃基）乙酮O-丙基肟
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):o1517-8. doi: 10.1107/S1600536809020844.
10
{5,5'-Dihydr-oxy-2,2'-[o-phenyl-enebis-(nitrilo-methyl-idyne)]diphenolato}nickel(II) dihydrate.二水合{5,5'-二羟基-2,2'-[邻苯撑双(次氮基甲基亚基)]二酚根合}镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 16;64(Pt 9):m1181-2. doi: 10.1107/S1600536808026093.

引用本文的文献

1
2-(4-Methoxy-phen-yl)-4,5-dihydro-1H-imidazole.2-（4-甲氧基苯基）-4,5-二氢-1H-咪唑
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 19;65(Pt 4):o798. doi: 10.1107/S1600536809009106.
2
2-(4,5-Dihydro-1H-imidazol-2-yl)-pyridine.2-（4,5-二氢-1H-咪唑-2-基）吡啶
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 19;65(Pt 4):o780. doi: 10.1107/S1600536809009131.

本文引用的文献

1
2-(3-Chloro-phen-yl)-4,5-dihydro-1H-imidazole.2-（3-氯苯基）-4,5-二氢-1H-咪唑
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 17;65(Pt 2):o338-9. doi: 10.1107/S1600536809001214.
2
2-[4-(4,5-Dihydro-1H-pyrrol-2-yl)phen-yl]-4,5-dihydro-1H-imidazole.2-[4-(4,5-二氢-1H-吡咯-2-基)苯基]-4,5-二氢-1H-咪唑
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):o2406. doi: 10.1107/S160053680803818X.
3
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
5
Enantioselective synthesis of alpha-amino nitriles from N-benzhydryl imines and HCN with a chiral bicyclic guanidine as catalyst.以手性双环胍为催化剂，由N-二苯甲基亚胺和HCN对映选择性合成α-氨基腈。
Org Lett. 1999 Jul 15;1(1):157-60. doi: 10.1021/ol990623l.
6
Effect of a novel anti-rheumatic drug, TA-383, on type II collagen-induced arthritis.新型抗风湿药物TA-383对Ⅱ型胶原诱导性关节炎的影响。
Int J Immunopharmacol. 1995 Jul;17(7):597-603. doi: 10.1016/0192-0561(95)00057-9.
7
Role of alpha 2-adrenoceptors and imidazoline-binding sites in the control of insulin secretion.α2-肾上腺素能受体和咪唑啉结合位点在胰岛素分泌调控中的作用。
Clin Sci (Lond). 1993 Dec;85(6):671-7. doi: 10.1042/cs0850671.
8
Compounds acting on alpha 1- and alpha 2- adrenoceptors: agonists and antagonists.
Med Res Rev. 1986 Oct-Dec;6(4):431-49. doi: 10.1002/med.2610060403.