Wang Jian-Ge, Qin Jian-Hua, Zhang Gui-Ying
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 4;65(Pt 3):m247. doi: 10.1107/S1600536809001676.
In the title compound, CoCl(2)(C(10)H(8)N(2)S)(2), the Co(II) atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octa-hedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the Co(II) centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intra-molecular C-H⋯N and C-H⋯Cl hydrogen bonds.
在标题化合物[CoCl₂(C₁₀H₈N₂S)₂]ₙ中,Co(II)原子位于一个对称中心上,由四个对称相关的二-4-吡啶基硫醚配体的四个N原子以及处于反位的两个Cl原子以扭曲的八面体几何构型进行六配位。桥连双齿二-4-吡啶基硫醚配体将Co(II)中心连接成三维网络。四个配位吡啶基团是分子内C-H⋯N和C-H⋯Cl氢键的供体和受体(N原子)。