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双(2-羟基-N'-亚异丙基苯甲酰肼基-κN',O)双(吡啶-κN)钴(II)

Bis(2-hydroxy-N'-isopropylidenebenzo-hydrazidato-κN',O)bis-(pyridine-κN)cobalt(II).

作者信息

Zhao Xiaojuan, Li Dacheng, Pan Yupeng

机构信息

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 28;65(Pt 4):m457-8. doi: 10.1107/S1600536809011015.

Abstract

In the title complex, [Co(C(10)H(11)N(2)O(2))(2)(C(5)H(5)N)(2)], the Co(II) atom lies on a centre of symmetry and adopts a distorted cis-CoO(2)N(4) octa-hedral geometry. The two acetone salicyloylhydrazone ligands are deprotonated and act as N,O-bidentate monoanionic ligands, forming the equatorial plane, while the axial positions are occupied by two N atoms of two pyridine mol-ecules. The complex presents O-H⋯N and C-H⋯N intra-molecular hydrogen bonds. Inter-molecular C-H⋯N and C-H⋯O inter-actions are also present in the crystal.

摘要

在标题配合物[Co(C₁₀H₁₁N₂O₂)₂(C₅H₅N)₂]中,Co(II)原子位于对称中心,采用扭曲的顺式CoO₂N₄八面体几何构型。两个丙酮水杨酰腙配体去质子化,作为N,O-双齿单阴离子配体,形成赤道平面,而轴向位置由两个吡啶分子的两个N原子占据。该配合物存在分子内O-H⋯N和C-H⋯N氢键。晶体中还存在分子间C-H⋯N和C-H⋯O相互作用。

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