双（5-氯喹啉-8-醇根合-κN，O）双（丙-2-醇根合-κO）钛（IV）
Bis(5-chloro-quinolin-8-olato-κN,O)bis-(propan-2-olato-κO)titanium(IV).
作者信息
Fazaeli Yousef, Najafi Ezzatollah, Amini Mostafa M, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 13;65(Pt 3):m271. doi: 10.1107/S1600536809004383.
The Ti(IV) atom in the title compound, [Ti(C(9)H(5)ClNO)(2)(C(3)H(7)O)(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa-hedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other. One C atom of one propan-2-olate group is disordered over two positions with occupancies of 0.733 (8):0.267 (8).
在标题化合物[Ti(C₉H₅ClNO)₂(C₃H₇O)₂]中，Ti(IV)原子被取代的喹啉-8-醇盐阴离子以扭曲的八面体几何构型螯合。氮供体原子呈顺式排列，异丙醇基团的氧原子也呈顺式排列；喹啉-8-醇盐基团的氧原子彼此呈反式排列。一个异丙醇基团的一个碳原子在两个位置上无序，占有率为0.733 (8):0.267 (8)。
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