（氨基乙酸根-κO,N）双（喹啉-8-醇根-κO,N）钴（III）甲醇溶剂化物
(Amino-acetato-κO,N)bis-(quinolin-8-olato-κO,N)cobalt(III) methanol solvate.
作者信息
Jing Bu-Qin, Meng Shuang-Ming, Han Jing, Wang Bin, Li Xue-Mei
机构信息
College of Chemistry and Chemical Engineering, Shanxi Datong University, Datong, Shanxi 037009, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 May 10;64(Pt 6):m795. doi: 10.1107/S1600536808013135.
In the crystal structure of the title compound, [Co(C(2)H(4)NO(2))(C(9)H(6)NO)(2)]·CH(3)OH, the Co(III) atom is chelated by two quinolin-8-olate and one glycinate anions in a distorted octa-hedral coordination geometry. The five-membered chelating glycinate ring assumes an envelope conformation. The complex mol-ecules are assembled by inter-molecular N-H⋯O hydrogen bonding.
在标题化合物[Co(C₂H₄NO₂)(C₉H₆NO)₂]·CH₃OH的晶体结构中，Co(III)原子由两个喹啉-8-醇盐和一个甘氨酸根阴离子以扭曲的八面体配位几何构型螯合。五元螯合甘氨酸环呈信封式构象。配合物分子通过分子间N-H⋯O氢键组装。
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