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双（高氯酸根-κO）四-双[1-（2-吡啶基）-4-（4-吡啶基甲基-κN）哌嗪]镉（II）

Bis(perchlorato-κO)tetra-kis[1-(2-pyridyl)-4-(4-pyridylmethyl-κN)piperazine]cadmium(II).

作者信息

Farnum Gregory A, Laduca Robert L

机构信息

Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825, USA.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 13;65(Pt 3):m274. doi: 10.1107/S1600536809004437.

DOI:10.1107/S1600536809004437
PMID:21582062
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968463/
Abstract

In the title compound, [Cd(ClO(4))(2)(C(15)H(18)N(4))(4)], the Cd(II) ion is coordinated in a slightly distorted octa-hedral environment by two trans monodentate perchlorate ligands and four 1-(2-pyrid-yl)-4-(4-pyridylmeth-yl)piperazine (pmpp) ligands. In the crystal structure, mol-ecules are organized into layers parallel to the ab plane by C-H⋯O inter-actions. Similar inter-actions promote the stacking of these layers into the three-dimensional crystal structure.

摘要

在标题化合物[Cd(ClO₄)₂(C₁₅H₁₈N₄)₄]中，Cd(II)离子由两个反式单齿高氯酸根配体和四个1-(2-吡啶基)-4-(4-吡啶基甲基)哌嗪(pmpp)配体在略微扭曲的八面体环境中配位。在晶体结构中，分子通过C—H⋯O相互作用排列成平行于ab平面的层。类似的相互作用促使这些层堆积成三维晶体结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb77/2968463/a77934ddde2a/e-65-0m274-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb77/2968463/07df0ba61148/e-65-0m274-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb77/2968463/f831b2515c7b/e-65-0m274-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb77/2968463/a77934ddde2a/e-65-0m274-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb77/2968463/07df0ba61148/e-65-0m274-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb77/2968463/f831b2515c7b/e-65-0m274-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb77/2968463/a77934ddde2a/e-65-0m274-fig3.jpg

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本文引用的文献

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