μ-双（二苯基胂基）甲烷-κAs:As'-双-[氯金（I）]
μ-Bis(diphenyl-arsino)methane-κAs:As'-bis-[chloridogold(I)].
作者信息
Monkowius Uwe, Zabel Manfred, Yersin Hartmut
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 18;65(Pt 3):m281. doi: 10.1107/S1600536809004802.
Abstract
The title structure, [Au(2)Cl(2)(C(25)H(22)As(2))], consists of discrete mol-ecules disposed about a crystallographic twofold axis. The Au atom exhibits a nearly linear coordination by As and Cl atoms. Au⋯Au inter-actions [3.4285Å(4) Å] and a weak intermolecular C-H⋯Cl hydrogen bond are present.
摘要
标题结构[Au₂Cl₂(C₂₅H₂₂As₂)]由围绕晶体学二重轴排列的离散分子组成。金原子通过砷和氯原子呈现出近似线性的配位。存在金⋯金相互作用[3.4285Å(4) Å]以及一个弱的分子间C-H⋯Cl氢键。
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