μ-1,2-双（二苯基膦基）苯-κP:P']双[氯化金（I）]
μ-1,2-Bis(diphenyl-phosphan-yl)benzene-κP:P']bis-[chloridogold(I).
作者信息
Yoshinari Nobuto, Kitani Naoki, Tsukuda Toshiaki, Konno Takumi
机构信息
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 24;67(Pt 1):m121. doi: 10.1107/S1600536810052803.
In the crystal structure of the non-solvate form of the title compound, [Au(2)Cl(2)(C(30)H(24)P(2))], two almost linear P-Au(I)-Cl units [175.87 (3) and 171.48 (3)°] are in a skewed arrangement with a Cl-Au⋯Au-Cl torsion angle of -65.29 (3)° so as to form an intra-molecular Au⋯Au inter-action [3.0563 (2) Å]. The complex mol-ecules are connected each other through inter-molecular C-H⋯π inter-actions, giving a sheet structure parallel to the bc plane.
在标题化合物[Au₂Cl₂(C₃₀H₂₄P₂)]的非溶剂化物形式的晶体结构中，两个近乎线性的P-Au(I)-Cl单元[175.87 (3)和171.48 (3)°]呈扭曲排列，Cl-Au⋯Au-Cl扭转角为-65.29 (3)°，从而形成分子内Au⋯Au相互作用[3.0563 (2) Å]。复杂分子通过分子间C-H⋯π相互作用相互连接，形成平行于bc平面的层状结构。
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