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氯代{2,2'-[丙烷-1,3-二亚基双(腈基亚甲基)]二酚根合-κO,N,N',O'}锰(III)

Chlorido{2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).

作者信息

Li Ming-Jie, Yan Peng-Fei, Li Guang-Ming, Li Hong-Feng

机构信息

School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 21;65(Pt 3):m306. doi: 10.1107/S1600536809005352.

DOI:10.1107/S1600536809005352
PMID:21582084
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968646/
Abstract

In the title complex, [Mn(C(17)H(16)N(2)O(2))Cl], the Mn(III) ion is coordinated by two O [Mn-O = 1.719 (2) and 1.813 (2) Å] and two N [Mn-N = 1.824 (2) and 1.931 (2) Å] atoms from the tetra-dentate Schiff base ligand and a chloride anion [Mn-Cl = 2.9634 (16) Å] in a square-pyramidal geometry. In the ligand, the two benzene rings form a dihedral angle of 68.06 (5)°.

摘要

在标题配合物[Mn(C₁₇H₁₆N₂O₂)Cl]中，Mn(III)离子由四齿席夫碱配体的两个O原子[Mn - O = 1.719 (2) Å和1.813 (2) Å]、两个N原子[Mn - N = 1.824 (2) Å和1.931 (2) Å]以及一个氯离子[Mn - Cl = 2.9634 (16) Å]配位，呈四方锥几何构型。在配体中，两个苯环形成的二面角为68.06 (5)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62e9/2968646/90bc7cc2c1bc/e-65-0m306-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62e9/2968646/90bc7cc2c1bc/e-65-0m306-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62e9/2968646/90bc7cc2c1bc/e-65-0m306-fig1.jpg

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