• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

（氰酸根-κN）{2,2'-[乙烷-1,2-二亚基双（腈基亚甲基）]二苯酚根-κO,N,N',O'}锰（III）的单斜晶型

Monoclinic form of (cyanato-κN){2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).

作者信息

Zhang Daopeng

机构信息

College of Chemical Engineering, Shandong University of Technology, Zibo 255049, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 24;66(Pt 12):m1656. doi: 10.1107/S1600536810048270.

DOI:10.1107/S1600536810048270
PMID:21589321
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011716/
Abstract

The title compound, [Mn(C(16)H(14)N(2)O(2))(NCO)], is a monoclinic polymorph of the previously published ortho-rhom-bic form [Lu et al. (2006 ▶). Inorg. Chem.45, 3538-3548]. The Mn(III) ion is chelated by a tetra-dentate Schiff base ligand and coordinated by the N atom of a cyanate ligand in a distorted square-pyramidal arrangement. In the crystal, there are short inter-molecular Mn⋯O(phenolate) distances of 2.752 (3) Å between pairs of inversion-related mol-ecules.

摘要

标题化合物[Mn(C₁₆H₁₄N₂O₂)(NCO)]是先前报道的正交晶系形式[Lu等人，(2006 ▶)。《无机化学》45, 3538 - 3548]的单斜晶系多晶型物。Mn(III)离子由一个四齿席夫碱配体螯合，并由一个氰酸酯配体的N原子以扭曲的四方锥排列配位。在晶体中，成对的反演相关分子之间存在短的分子间Mn⋯O(酚盐)距离，为2.752(3) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8654/3011716/e5249be71cab/e-66-m1656-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8654/3011716/e5249be71cab/e-66-m1656-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8654/3011716/e5249be71cab/e-66-m1656-fig1.jpg

相似文献

1
Monoclinic form of (cyanato-κN){2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).（氰酸根-κN）{2,2'-[乙烷-1,2-二亚基双（腈基亚甲基）]二苯酚根-κO,N,N',O'}锰（III）的单斜晶型
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 24;66(Pt 12):m1656. doi: 10.1107/S1600536810048270.
2
Bis{μ-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}bis-[(thio-cyanato)manganese(III)].双{μ-2,2'-[乙烷-1,2-二基双(腈基亚甲基)]二酚根合}双[(硫氰酸根合)锰(III)]。
Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 14;64(Pt 4):m543. doi: 10.1107/S1600536808003577.
3
Azido{4,4'-dibromo-2,2'-[ethane-1,2-diyl-bis(nitrilo-methanylylidene)]diphenol-ato-κO,N,N',O'}manganese(III).叠氮基{4,4'-二溴-2,2'-[乙烷-1,2-二基-双(腈基亚甲基)]二酚根合-κO,N,N',O'}锰(III)
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 12;67(Pt 3):m322. doi: 10.1107/S1600536811004594.
4
Bis{μ-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}bis-[(thio-cyanato-κN)iron(III)].双{μ-2,2'-[乙烷-1,2-二基双(腈基亚甲基)]二酚根合}双[(硫氰酸根-κN)铁(III)]
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 16;64(Pt 8):m1034. doi: 10.1107/S1600536808021892.
5
Aqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}(formato-κO)manganese(III) dihydrate.水合-{6,6'-二甲氧基-2,2'-[乙烷-1,2-二基双(亚氨甲基亚基)]二酚根合-κO,N,N',O'}(甲酸根合-κO)锰(III)二水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m746. doi: 10.1107/S1600536811017648. Epub 2011 May 14.
6
The cocrystal aqua-chlorido{6,6'-di-tert-butyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}-manganese(III)-chlorido{6,6'-di-tert-butyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}(methanol-κO)manganese(III) (1/1).氯代水合{6,6'-二叔丁基-2,2'-[1,2-亚苯基双(次氮基甲基亚基)]二酚根合-κO,N,N',O'}-锰(III)-氯代{6,6'-二叔丁基-2,2'-[1,2-亚苯基双(次氮基甲基亚基)]二酚根合-κO,N,N',O'}(甲醇-κO)锰(III) (1/1)
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 4;64(Pt 5):m626-7. doi: 10.1107/S1600536808006818.
7
Aqua-{6,6-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) acetonitrile solvate.水合-{6,6-二甲氧基-2,2'-[丙烷-1,3-二基双(腈基亚甲基)]二酚根合-κO,N,N',O'}铜(II)乙腈溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 21;65(Pt 12):m1658. doi: 10.1107/S1600536809049137.
8
Chlorido{4,4',6,6'-tetra-tert-butyl-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).氯代{4,4',6,6'-四叔丁基-2,2'-[邻苯撑双(亚氨甲基亚基)]二酚根合-κO,N,N',O'}锰(III)
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 28;65(Pt 12):m1692-3. doi: 10.1107/S1600536809050314.
9
Chlorido{6,6'-dimethyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III) mono-hydrate.一水合氯代{6,6'-二甲基-2,2'-[1,2-亚苯基双(腈基亚甲基)]二酚根合-κO,N,N',O'}锰(III)
Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 12;64(Pt 4):m535-6. doi: 10.1107/S160053680800620X.
10
Chlorido{2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).氯代{2,2'-[丙烷-1,3-二亚基双(腈基亚甲基)]二酚根合-κO,N,N',O'}锰(III)
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 21;65(Pt 3):m306. doi: 10.1107/S1600536809005352.

本文引用的文献

1
Bis{μ-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}bis-[(thio-cyanato)manganese(III)].双{μ-2,2'-[乙烷-1,2-二基双(腈基亚甲基)]二酚根合}双[(硫氰酸根合)锰(III)]。
Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 14;64(Pt 4):m543. doi: 10.1107/S1600536808003577.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Syntheses, crystal structures, and magnetic characterization of five new dimeric manganese(III) tetradentate Schiff base complexes exhibiting single-molecule-magnet behavior.
五种呈现单分子磁体行为的新型二聚体锰（III）四齿席夫碱配合物的合成、晶体结构及磁性表征
Inorg Chem. 2006 May 1;45(9):3538-48. doi: 10.1021/ic051648l.