双（μ-N，N-二甲基二硫代氨基甲酸盐-κS，S'：S）双[（N，N-二甲基二硫代氨基甲酸盐-κS，S'）铜（II）]
Bis(μ-N,N-dimethyl-dithio-carbamato-κS,S':S)bis-[(N,N-dimethyl-dithio-carbamato-κS,S')copper(II)].
作者信息
Fan Le-Qing, Wu Ji-Huai
机构信息
Institute of Materials Physical Chemistry and the Key Laboratory for Functional Materials of Fujian Higher Education, Huaqiao University, Quanzhou, Fujian 362021, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 25;65(Pt 3):m319. doi: 10.1107/S1600536809006230.
In the centrosymmetric dimeric title compound, [Cu(2)(C(3)H(6)NS(2))(4)], the Cu(II) atom is five-coordinate in a square-pyramidal environment. The basal coordination positions are occupied by four S atoms from two dimethyl-dithio-carbamate ligands and the apical coordination position is occupied by an S atom also bonded to the other Cu atom.
在中心对称的二聚体标题化合物[Cu₂(C₃H₆NS₂)₄]中，Cu(II)原子在四方锥环境中呈五配位。其基础配位位置由来自两个二甲基二硫代氨基甲酸盐配体的四个硫原子占据，顶端配位位置由一个也与另一个铜原子键合的硫原子占据。
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