Du Guihuan, Liu Zuli, Chu Qian, Li Zhen, Zhang Suming
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 25;65(Pt 3):o607-8. doi: 10.1107/S1600536809006205.
In the title compound, 2C(4)H(7)N(2) (+)·C(4)H(4)O(4) (2-)·C(4)H(6)O(4), the asymmetric unit consists of two 4-methyl-imidazolium cations, one succinate dianion and one netrual succinic acid mol-ecule and within the latter components, the C-O, C=O and C O bonds are clearly evidenced from their relative distances. In the crystal structure, the individual components are linked by inter-molecular N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds into a two-dimensional network parallel to the (101) plane in which R(3) (3)(9), R(3) (3)(12) and R(4) (4)(18) hydrogen-bond motifs are present.
在标题化合物2C₄H₇N₂⁺·C₄H₄O₄²⁻·C₄H₆O₄中,不对称单元由两个4-甲基咪唑鎓阳离子、一个琥珀酸二阴离子和一个中性琥珀酸分子组成,在后者的组分中,C—O、C═O和C—O键可从它们的相对距离清晰地得到证实。在晶体结构中,各个组分通过分子间的N—H⋯O、O—H⋯O和C—H⋯O氢键连接成平行于(101)平面的二维网络,其中存在R₃³(9)、R₃³(12)和R₄⁴(18)氢键模式。