• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

E-[4-(β-D-吡喃阿洛糖氧基)苯基]-1-(4-氯苯基)丙-2-烯酮乙醇溶剂化物

E-[4-(β-d-Allopyranos-yloxy)phen-yl]-1-(4-chloro-phen-yl)prop-2-enone ethanol solvate.

作者信息

Yang Cong-Ling, Luo Hua-Ling, Yin Xiu-Juan, Li Ying, Yin Shu-Fan

机构信息

College of Chemistry, Sichuan University, Chengdu 610064, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 28;65(Pt 3):o634. doi: 10.1107/S1600536809006424.

DOI:10.1107/S1600536809006424
PMID:21582283
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968659/
Abstract

The title compound, C(21)H(21)ClO(7)·C(2)H(5)OH was synthesized by the condensation reaction between helicid [systematic name: 4-(β-d-allopyranos-yloxy)benzaldehyde] and 4-chloro-aceto-phen-one in ethanol. In the mol-ecular structure, the pyran-oside ring adopts a chair conformation. In the crystal structure, the molecules are linked by inter-molecular O-H⋯O hydrogen bonds involving the OH groups from the pyran-oside unit and from the ethanol solvent mol-ecule.

摘要

标题化合物C(21)H(21)ClO(7)·C(2)H(5)OH是通过在乙醇中，蛇床子素[系统名称：4-(β-D-阿洛吡喃糖氧基)苯甲醛]与4-氯苯乙酮之间的缩合反应合成的。在分子结构中，吡喃糖苷环呈椅式构象。在晶体结构中，分子通过分子间O-H⋯O氢键相连，这些氢键涉及吡喃糖苷单元和乙醇溶剂分子中的OH基团。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/73a1/2968659/0cbe951f0aff/e-65-0o634-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/73a1/2968659/0cbe951f0aff/e-65-0o634-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/73a1/2968659/0cbe951f0aff/e-65-0o634-fig1.jpg

相似文献

1
E-[4-(β-d-Allopyranos-yloxy)phen-yl]-1-(4-chloro-phen-yl)prop-2-enone ethanol solvate.E-[4-(β-D-吡喃阿洛糖氧基)苯基]-1-(4-氯苯基)丙-2-烯酮乙醇溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 28;65(Pt 3):o634. doi: 10.1107/S1600536809006424.
2
(E)-1-(4-Chloro-phen-yl)-3-[4-(2,3,4,6-tetra-O-acetyl-β-d-allopyranos-yloxy)phen-yl]prop-2-en-1-one.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):o310. doi: 10.1107/S1600536809055652.
3
(E)-4-(β-d-Allopyran-os-yloxy)cinnamyl 4-bromo-phenyl ketone ethanol solvate.（E）-4-（β-D-阿洛吡喃糖氧基）肉桂基 4-溴苯基酮乙醇溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 31;65(Pt 8):o2044. doi: 10.1107/S1600536809029687.
4
N-[4-(β-d-Allopyranos-yloxy)benzyl-idene]methyl-amine.N-[4-(β-D-吡喃阿洛糖氧基)亚苄基]甲胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 10;65(Pt 2):o290. doi: 10.1107/S1600536809000944.
5
Crystal structure of (Z)-3-[5-chloro-2-(prop-2-yn-yloxy)phen-yl]-3-hy-droxy-1-[4-(tri-fluoro-meth-yl)phen-yl]-prop-2-en-1-one.（Z）-3-[5-氯-2-（丙-2-炔-基氧基）苯基]-3-羟基-1-[4-（三氟甲基）苯基]丙-2-烯-1-酮的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jul 8;71(Pt 8):o556-7. doi: 10.1107/S2056989015012748. eCollection 2015 Aug 1.
6
(E)-1-{4-[Bis(4-meth-oxy-phen-yl)meth-yl]piperazin-1-yl}-3-(3,4-dieth-oxy-phen-yl)prop-2-en-1-one ethanol disolvate.（E）-1-{4-[双（4-甲氧基苯基）甲基]哌嗪-1-基}-3-（3,4-二乙氧基苯基）丙-2-烯-1-酮乙醇溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o298. doi: 10.1107/S1600536811055796. Epub 2012 Jan 7.
7
1-[4-(2,3,4,6-Tetra-O-acetyl-β-d-allo-pyranos-yloxy)benzyl-idene]thio-semi-carbazide.1-[4-(2,3,4,6-四-O-乙酰基-β-D-阿洛吡喃糖氧基)亚苄基]硫代氨基脲
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):o679. doi: 10.1107/S1600536809007260.
8
(E)-3-[4-(Dec-yloxy)phen-yl]-1-(4-hydroxy-phen-yl)prop-2-en-1-one.（E）-3-[4-（癸氧基）苯基]-1-（4-羟基苯基）丙-2-烯-1-酮
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):o1092-3. doi: 10.1107/S160053680901441X.
9
Bis[4-(4-chloro-phen-yl)-4-hydroxy-piperidinium] dipicrate dimethyl sulfoxide solvate.二苦味酸双[4-(4-氯苯基)-4-羟基哌啶鎓]二甲亚砜溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 30;66(Pt 5):o1212-3. doi: 10.1107/S1600536810015187.
10
(E)-1-[4-(Hex-yloxy)phen-yl]-3-(3-hy-droxy-phen-yl)prop-2-en-1-one.（E）-1-[4-（己氧基）苯基]-3-（3-羟基苯基）丙-2-烯-1-酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 24;66(Pt 12):o3275-6. doi: 10.1107/S1600536810047768.

引用本文的文献

1
(E)-4-(β-d-Allopyran-os-yloxy)cinnamyl 4-bromo-phenyl ketone ethanol solvate.（E）-4-（β-D-阿洛吡喃糖氧基）肉桂基 4-溴苯基酮乙醇溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 31;65(Pt 8):o2044. doi: 10.1107/S1600536809029687.
2
(E)-1-(4-Chloro-phen-yl)-3-[4-(2,3,4,6-tetra-O-acetyl-β-d-allopyranos-yloxy)phen-yl]prop-2-en-1-one.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):o310. doi: 10.1107/S1600536809055652.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.