Fang Hua, Fang Mei-Juan, Xu Ying, Yu Wen-Cheng, Zhao Yu-Fen
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 28;65(Pt 3):o642. doi: 10.1107/S1600536809006382.
The title compound, C(20)H(26)NO(4)P, has been obtained by the reaction of benzoyl chloride and diisoprop-yl[amino-(phen-yl)meth-yl]phospho-nate. The dihedral angle between the planes of the benzoyl-amino group and the phenyl ring is 77.0 (2)°. The crystal structure is stabilized by strong inter-molecular N-H⋯O hydrogen bonds between the doubly bonded phosphoryl O atom and the amide N atom which link the mol-ecules into pairs about a center of symmetry.
标题化合物C(20)H(26)NO(4)P是通过苯甲酰氯与二异丙基[氨基-(苯基)甲基]膦酸酯反应得到的。苯甲酰氨基平面与苯环平面之间的二面角为77.0 (2)°。晶体结构通过双键磷酰O原子与酰胺N原子之间强烈的分子间N-H⋯O氢键得以稳定,这些氢键将分子围绕一个对称中心连接成成对结构。