聚[μ-氯代-[μ(4)-5-(4-吡啶基)四唑合]二铜(I)]
Poly[μ-chlorido-[μ(4)-5-(4-pyrid-yl)tetra-zol-ato]dicopper(I)].
作者信息
Wang Cun-Kuan, Li Xiao-Yan
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):m363. doi: 10.1107/S1600536809006564.
Abstract
The title three-dimensional coordination polymer, Cu(2)Cl(C(6)H(4)N(5)), is the product of the hydro-thermal reaction of CuCl(2)·2H(2)O and 5-(4-pyrid-yl)-1H-tetra-zole (4-Hptz). The two independent Cu(I) ions are coordinated in distorted tetra-hedral and distorted trigonal coordination environments. In the unique 5-(4-pyrid-yl)-1H-tetra-zolate ligand, the dihedral angle between the pyridine and tetra-zole rings is 17.3 (2)°.
摘要
标题为三维配位聚合物[Cu₂Cl(C₆H₄N₅)]ₙ，是CuCl₂·2H₂O与5-(4-吡啶基)-1H-四唑(4-Hptz)水热反应的产物。两个独立的Cu(I)离子在扭曲的四面体和扭曲的三角配位环境中配位。在独特的5-(4-吡啶基)-1H-四唑酸根配体中，吡啶环和四唑环之间的二面角为17.3 (2)°。
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