Wang Bo
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 1;65(Pt 8):m861. doi: 10.1107/S160053680902443X.
The title compound, [Fe(C(6)H(4)N(5))(2)Cl(H(2)O)], was synthesized by hydro-thermal reaction of FeCl(3) with 2-(1H-tetra-zol-5-yl)pyridine. The iron(III) metal centre exhibits a distorted octa-hedral coordination geometry provided by four N atoms from two bidentate organic ligands, one water O atom and one chloride anion. The pyridine and tetra-zole rings are nearly coplanar [dihedral angles = 4.32 (15) and 5.04 (14)°]. In the crystal structure, inter-molecular O-H⋯N hydrogen bonds link the complex mol-ecules into a two-dimensional network parallel to (100).
标题化合物[Fe(C₆H₄N₅)₂Cl(H₂O)]通过FeCl₃与2-(1H-四唑-5-基)吡啶的水热反应合成。铁(III)金属中心呈现出扭曲的八面体配位几何构型，由两个双齿有机配体的四个N原子、一个水O原子和一个氯离子提供。吡啶环和四唑环几乎共面[二面角分别为4.32 (15)°和5.04 (14)°]。在晶体结构中，分子间的O—H⋯N氢键将配合物分子连接成平行于(100)的二维网络。
